Interionic interactions of glycine, l-alanine, glycylglycine and phenylalanine in aqueous 1-hexyl-3-methylimidazolium chloride ionic liquid solutions at T = (288.15 to 308.15) K: Volumetric, speed of sound and viscometric measurements
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- 作者：Chanda Chadha ; Meenu Singla ; Harsh Kumar ; h.786.man@gmail.com" class="auth_mail" title="E-mail the corresponding author ; manchandah@nitj.ac.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：1-Hexyl-3-methylimidazolium chloride ; Apparent molar property ; Hydration number ; Viscosity B-coefficient ; Amino acid
- 刊名：Journal of Molecular Liquids
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：218
- 期：Complete
- 页码：68-82
- 全文大小：1768 K
文摘
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New ρ, u and η measurements of amino acids in aqueous solution of [C6mim][Cl].
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10">Positive Vϕ0 values for amino acids/peptide increases with the increase in temperature.
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15">Magnitude of negative values of κϕ,s decreases with increase in temperature and concentration of [C6mim][Cl].
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Decrease in hydration number with [C6mim][Cl] concentration shows interaction between ions.
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Large values of Δμ2o⁎ predicts amino acids/peptide as structure-maker.