A high-rate and long cycling life cathode for rechargeable lithium-ion batteries: hollow LiNi_0.5Mn_0.5O₂ nano/micro hierarchical microspheres

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• 作者：Jili Li^a ; ^{lijili328@126.com" class="auth_mail" title="E-mail the corresponding author} ; Lin Wan^a ; Chuanbao Cao^b
• 关键词：Hollow microspheres ; Nano/micro hierarchical structures ; LiNi0.5Mn0.5O2 cathode ; High-rate capability ; Lithium-ion batteries
• 刊名：Electrochimica Acta
• 出版年：2016
• 出版时间：10 February 2016
• 年：2016
• 卷：191
• 期：Complete
• 页码：974-979
• 全文大小：1734 K

文摘

A rechargeable lithium-ion batteries cathode LiNi_0.5Mn_0.5O₂ with hollow nano/micro hierarchical microspheres (LNMO-HS) is prepared. LNMO-HS with diameters of about 1 μm is composed of approximately 100 nm primary nanoparticles. The initial discharge capacity of LNMO-HS cathode is as high as 181.5 mAh g⁻¹ at 1 C between 2.5 and 4.5 V. The corresponding capacity retention is 96.3% during 100 charge and discharge cycles. The reversible discharge capacities are 152.2 (10 C) and 134.6 mAh g⁻¹ (15 C), respectively. After 1000 cycles at 15 C, the capacity retention of LNMO-HS cathode is up to 95.5%. The superior rate capability and cyclability of LNMO-HS cathode can be attributed to the distinctive hollow nano/micro hierarchical microspherical structures. It could not only effectively reduce the paths of Li ions diffusion, increase contact area between electrodes and electrolyte but also buffer the volume changes during Li ions intercalation/deintercalation processes.