A novel glycosylation concept; microwave-assisted acetal-exchange type glycosylations from methyl glycosides as donors
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- 作者：Yoshimura ; Yayoi ; Shimizu ; Hiroki ; Hinou ; Hiroshi ; Nishimura ; Shin-Ichiro
- 关键词：Microwave ; Glycosylation ; Carbohydrate ; Methyl glycoside
- 刊名：Tetrahedron Letters
- 出版年：2005
- 出版时间：July 11, 2005
- 年：2005
- 卷：46
- 期：28
- 页码：4701-4705
- 全文大小：120 K
文摘
Efficient microwave-assisted glycosylations from methyl glucopyranosides are described. We have discussed the effects of microwave irradiation on this unique glycoside exchanging reaction from view points such as amount of Lewis acid promoters and acceptors, hydroxyl protecting groups of methyl glucopyranosides donors for reactivity, and neighboring effect.