In situ evolved gas analysis assisted thermogravimetric (TG-FTIR and TG/DTA-MS) studies on non-activated copper benzene-1,3,5-tricarboxylate

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• 作者：Andrea Domá ; n^a ; ^{doman.andrea@mail.bme.hu} ; Já ; nos Madará ; sz^b ; ^{madarasz@mail.bme.hu} ; Krisztina Lá ; szló ; ^a ; ^{klaszlo@mail.bme.hu}
• 关键词：HKUST-1 ; Metal organic framework ; MOF ; Simultaneous TG/DTA-MS ; TG-FTIR ; XRD
• 刊名：Thermochimica Acta
• 出版年：2017
• 出版时间：10 January 2017
• 年：2017
• 卷：647
• 期：Complete
• 页码：62-69
• 全文大小：1946 K
• 卷排序：647

文摘

Thermogravimetry, coupled with in situ MS and FTIR analyses of the evolved gas. Results from oxidative and inert media allow conclusions to be drawn about stoichiometry. Conversion of Cu2O to CuO by 800 °C confirmed by XRD. All the retained water can be removed by 150 °C. Ethanol release (150–250 °C) suggests ester formation on preventing crystal growth.