N,N-disulfo-1,1,3,3-tetramethylguanidinium carboxylate ionic liquids as reusable homogeneous catalysts for multicomponent synthesis of tetrahydrobenzo[a]xanthene and tetrahydrobenzo[a]acridine derivatives
文摘
Three new members of TMG-based N,N-disulfonic ILs are prepared. TGA analysis shows their thermal stability within the range of 270–300 °C. The Hammett study determines the acidity order of all the TMG-based ILs. They are optimized as recyclable homogeneous catalysts for heterocycle synthesis. It describes the first four-component synthesis of tetrahydrobenzo[a]acridinones.