Aerobic oxidation of amines to imines catalyzed by a ruthenium complex under solvent-free conditions
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- 作者：Yuecheng Zhang ; Fei Lu ; Rong Huang ; Hongyu Zhang ; Jiquan Zhao ; zhaojq@hebut.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ruthenium complex ; Imines ; Benzylamines ; Aerobic oxidation
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：5 June 2016
- 年：2016
- 卷：81
- 期：Complete
- 页码：10-13
- 全文大小：3516 K
文摘
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[Et3NH]2[Ru(dipic)Cl3] showed high efficiency in aerobic oxidation of amines to imines.
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The imines can be obtained in high yield under air and solvent-free conditions.
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This protocol is an atom-economical green process and tolerates various substrates.
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[Et3NH]2[Ru(dipic)Cl3] is readily available.