Synthesis of Carbon-Encapsulated Iron Nanoparticles by Gaseous Detonation of Hydrogen and Oxygen at Different Temperatures within Detonation Tube
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- 作者：Yan Honghao ; Hun Changhong ; Li Xiaojie ; 923309973@qq.com" class="auth_mail" title="E-mail the corresponding author ; Zhao Tiejun
- 关键词：gaseous detonation ; ferrocene ; hydrogen and oxygen gas ; detonation tube
- 刊名：Rare Metal Materials and Engineering
- 出版年：2015
- 出版时间：September 2015
- 年：2015
- 卷：44
- 期：9
- 页码：2152-2155
- 全文大小：985 K
文摘
Using ferrocene as precursor, the mixed gas of hydrogen and oxygen as the source of explosion, the carbon encapsulated iron nanoparticles were prepared in a detonation tube. The influences of initial reactive temperature and heat treatment on the products of particles were studied. The characteristics of detonation products were tested by X-ray diffraction (XRD), transmission electron microscope (TEM), and vibrating sample magnetometer (VSM). Results show that the carbon encapsulated nanoparticles exhibit the shapes of sphere or spheroid. With reaction temperature increasing, the grain sizes of carbon encapsulated iron nanoparticles are 30∼50 nm and tend to be uniform, which indicates that the initial reaction temperature directly affects the grain sizes of the generated particles. Through the analysis of magnetic hysteresis loops of detonation products, the saturated magnetization (Ms) decreases as the temperature of heat treatment increases, and the hysteresis loops are in a relatively “thin” shape, but still have higher coercivity, indicating that the synthesized carbon-encapsulated iron nanomaterials present the dual natures of the hard magnetic and the paramagnetic.