Tuning the entanglement of coordination polymers by controlling the steric hindrance of organic linkers

详细信息    查看全文

• 作者：Xianmin Guo ; Huadong Guo ; ^{hdxmguo@yahoo.cn} ; Hengye Zou ; Yanjuan Qi ; Chunming Liu
• 关键词：Coordination polymers ; Entanglement ; Steric hindrance
• 刊名：Journal of Molecular Structure
• 出版年：2013
• 出版时间：5 July, 2013
• 年：2013
• 卷：1043
• 期：Complete
• 页码：116-120
• 全文大小：1972 K

文摘

In this paper, through the adjustment of alkyls attached to fluorene-based dicarboxylic acids, two Cd(II) coordination polymers featuring different entangled structures have been synthesized under the same solvothermal condition, which shows that the rational modulation of organic ligands¡¯ steric hindrance is an effective approach to the construction of novel entangled framework.