Influence of CNTs on Pebax permeability increase was MWNTs-NH2>MWNTs-OH>MWNTs.
The optimized Pebax/CNTs MMMs were further modified with GTA.
Diffusivities and solubilities of Pebax/MWNTs-NH2/GTA MMMs increased with GTA.
CO2 permeability of P10CN1G25 increased ten times than Pebax.