Platinum group element abundances in the upper continental crust revisited - New constraints from analyses of Chinese loess

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• 作者：Jung-Woo Park ; Zhaochu Hu ; Shan Gao ; Ian H. Campbell ; Hujun Gong
• 刊名：Geochimica et Cosmochimica Acta
• 出版年：2012
• 出版时间：15 September, 2012
• 年：2012
• 卷：93
• 期：Complete
• 页码：63-76
• 全文大小：1033 K

文摘

Platinum group element (PGE) abundances in the upper continental crust (UCC) are poorly constrained with published values varying by up to an order of magnitude. We evaluated the validity of using loess to estimate PGE abundances in the UCC by measuring these elements in seven Chinese loess samples using a precise method that combines NiS fire assay with isotope dilution. Major and trace elements of the Chinese loess show a typical upper crustal composition and PGE abundances are consistent with literature data on Chinese loess, except for Ru, which is a factor of 10 lowe than published values. We suggest that the high Ru data and Ru_N/Ir_N values of Chinese loess reported by (Geochem. Geophys. Geosys. 2, 2001GC000172) are an analytical artifact, rather than a true geochemical characteristic of loess because likely sources of loess are not significantly enriched in Ru and transport and deposition processes cannot preferentially enrich Ru in loess. The effect of eolian fractionation on PGE abundances in loess appears to be limited because Chinese loess from different locations shows similar PGE patterns and concentrations. This conclusion is supported by strong positive correlations between the PGE (except for Pt) and other compatible elements such as Fe₂O₃, Ni, Cr, Co. Using a compilation of PGE data for loess from China, Argentina and Europe, including our data but excluding one sample with an anomalously high Pt content, we propose average PGE abundances for global loess of Ir = 0.022 ppb (ng/g), Ru = 0.030 ppb, Rh = 0.018 ppb, Pt = 0.599 ppb, and Pd = 0.526 ppb, and suggest that these are the best current estimates for the PGE abundances of the UCC.