Hydrogenolysis of glycerol over Cu-substituted hydrocalumite mediated catalysts
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- 作者：Liping Zheng ; Shuixin Xia ; Zhaoyin Hou ; zyhou@zju.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Hydrocalumite ; Basic sites ; Glycerol ; Hydrogenolysis
- 刊名：Applied Clay Science
- 出版年：2015
- 出版时间：December 2015
- 年：2015
- 卷：118
- 期：Complete
- 页码：68-73
- 全文大小：603 K
文摘
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Wellcrystallized hydrocalumite [CuxCayAl(OH)2x + 2y + 2]NO3·nH2O (x < 1.5) was synthesized.
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Cu dispersed highly in the matrix of calcined hydrocalumite.
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Cu-substituted hydrocalumite mediated catalyst is active for the hydrogenolysis of glycerol.
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The specific activity of surface Cu increased with the basicity of catalysts.