Stability and partial oligomerization of naphthalene under high pressure at room temperature
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- 作者：Ayako Shinozakia ; shinozaki.ayako@f.mbox.nagoya-u.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Koichi Mimuraa ; Tamihito Nishidab ; Toru Inouec ; Satoshi Nakanod ; Hiroyuki Kagie
- 关键词：High pressure ; Polycyclic aromatic hydrocarbons ; XRD ; GC/MS
- 刊名：Chemical Physics Letters
- 出版年：2016
- 出版时间：1 October 2016
- 年：2016
- 卷：662
- 期：Complete
- 页码：263-267
- 全文大小：636 K
文摘
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Naphthalene retained its crystal phase at around 20 GPa with a amorphous phase.
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Naphthalene partially oligomerized above 15 GPa at room temperature.
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The main reaction products could be divided into three types.
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1,2′-Binaphthyl is the most abundant product in three binaphthyl isomers.
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The oligomerization would be promoted with decreasing intermolecular distance.