In situ FTIR studies on the electrochemical hydrodechlorination of 3,4,5,6-tetrachloropicolinic acid on Ag cathode

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• 作者：Chun An Ma ; Mei Chao Li ; Yan Na Liu ; Ying Hua Xu
• 关键词：3 ; 4 ; 5 ; 6-Tetrachloropicolinic acid ; Electrochemical hydrodechlorination ; In situ FTIR ; Ag ; 3 ; 6-Dichloropicolinic acid
• 刊名：Electrochimica Acta
• 出版年：2010
• 出版时间：30 March 2010
• 年：2010
• 卷：55
• 期：9
• 页码：3171-3174
• 全文大小：516 K

文摘

The electrochemical hydrodechlorination reaction from starting material 3,4,5,6-tetrachloropicolinic acid (3,4,5,6-TCP) to the end product 3,6-dichloropicolinic acid (3,6-DCP) was investigated by cyclic voltammetry and in situ Fourier transform infrared spectroscopy (in situ FTIR). Compared with copper and glassy carbon, Ag cathode showed a high electrocatalytic activity for the irreversible reduction process of 3,4,5,6-TCP in NaOH aqueous solution. In situ FTIR results suggested that electrochemical hydrodechlorination took place in the 4- or 5-position of 3,4,5,6-TCP on Ag cathode after receiving an electron to get mixed trichloropicolinic acid free radical, which could receive another electron and give 3,5,6-trichloropicolinic acid (3,5,6-TCP) and 3,4,6-trichloropicolinic acid (3,4,6-TCP) at the potential more positive than −1000 mV afterwards. Finally, 3,5,6-TCP and 3,4,6-TCP were further dechlorinated to produce 3,6-dichloropicolinic acid (3,6-DCP) at the potential more negative than −1000 mV. Further studies of preparative electrolysis experiments by constant current electrolysis were carried out. The results were in good agreement with those from in situ FTIR investigations.