For the first time, ZIF-67 containing MMMs were studied for C3H6/C3H8 separations. The intrinsic C3H6/C3H8 separation performance of ZIF-67 was estimated. Energetic selectivity-enhanced molecular sieving behavior of ZIF-67 was demonstrated. Defect-free 6FDA-DAM/ZIF-67 MMMs effectively retarded physical aging process.