Co-doped Pb-Ti/MoS2 composite coatings were successfully fabricated by unbalanced magnetron sputtering system. Co-doped Pb-Ti/MoS2 composite coatings showed lower friction coefficient and longer wear life in both humid and vacuum environments than that of single-doped ones. The wear behaviours of Pb-Ti/MoS2 composite coatings with the increase of Pb content is in accordance with the variation in H/E ratio that higher H/E is corresponding to the lower wear rate of coating.