Synthesis of zeolitic imidazolate framework-8 particles of controlled sizes, shapes, and gate adsorption characteristics using a central collision-type microreactor

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• 作者：Satoshi Watanabe ; ^{nabe@cheme.kyoto-u.ac.jp} ; Shuji Ohsaki ; Tatsuya Hanafusa ; Kento Takada ; Hideki Tanaka ; Kazuhiro Mae ; Minoru T. Miyahara ; ^{miyahara@cheme.kyoto-u.ac.jp}
• 关键词：Metal-organic frameworks ; Gate adsorption ; Microreactors ; Crystal growth ; Nucleation ; Mixing
• 刊名：Chemical Engineering Journal
• 出版年：2017
• 出版时间：1 April 2017
• 年：2017
• 卷：313
• 期：Complete
• 页码：724-733
• 全文大小：3275 K
• 卷排序：313

文摘

ZIF-8 particles are synthesized using a central collision-type microreactor. Excellent mixing performance of the microreactor enables reproducible synthesis. Particle size is determined by the mixing process in the microreactor. Particle shape is controlled by temperature during the aging process after mixing. Gate adsorption properties of ZIF-8 particles depends on the particle size and shape.