Transfer hydrogenation of ketones catalyzed by complexes of ruthenium(II) with the heterotridentate [P,N,O] ligands (S)-2-[{2-(diphenylphosphanyl)benzylidene}amino]propan-1-ol, (S)-2-[{2-(diphenylphosphanyl)benzyl}amino]propan-1-ol or the [P,N,S] ligand (S)-2-(dimethylamino)-1-(diphenylphosphino)-3-(methylthio)propane

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• 作者：Abeer H. Obaid¹ ; Nuru G. Stracey² ; Christopher D. Incarvito³ ; Brandon Q. Mercado¹ ; ⁴ ; Jonathan Parr ; ^{jonathan.parr@yale.edu}
• 关键词：Transfer hydrogenation ; Ruthenium ; Heterotridentate ligands ; Dimethylamine borane ; X-ray crystallography
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：830
• 期：Complete
• 页码：74-84
• 全文大小：1004 K
• 卷排序：830

文摘

Synthesis of three new ruthenium(II) complexes with chiral [P,N,E] (E = O, S) ligands. Transfer hydrogenation of aryl ketones using dimethylamine borane as hydrogen donor without an intert atmosphere. 1H NMR detection of a ruthenium hydride in the reaction mixture.