Physico-chemical properties of MnII complexes formed with cis- and trans-DO2A: thermodynamic, electrochemical and kinetic studies
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- 作者：Zoltá ; n Gardaa ; Attila Forgá ; csa ; Quyen N. Dob ; Ferenc K. Ká ; lmá ; na ; c ; d ; Sarolta Timá ; ria ; 1 ; Zsolt Baranyaia ; Lorenzo Teie ; Imre Tó ; tha ; Zoltá ; n Ková ; csf ; Gyula Tircsó ; a ; gyula.tircso@science.unideb.hu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Magnetic resonance imaging (MRI) ; Contrast agents (CAs) ; Manganese ; Thermodynamic stability ; Inertness ; Electrochemistry
- 刊名：Journal of Inorganic Biochemistry
- 出版年：2016
- 出版时间：October 2016
- 年：2016
- 卷：163
- 期：Complete
- 页码：206-213
- 全文大小：663 K
文摘
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The stability constants of MnII complexes agree well with those published in the literature.
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The redox potentials of the complexes follow the expected (based on the structure) order.
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Both MnII complexes are inert and they primarily undergo acid catalyzed dissociation.
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The positions of the acetate moieties have little effect on the properties of the complexes.