Preparation of BiFeO₃ films by wet chemical method and their characterization

详细信息    查看全文

• 作者：V. Fruth ; E. Tenea ; M. Gartner ; M. Anastasescu ; D. Berger ; R. Ramer ; M. Zaharescu
• 关键词：Films ; Spectroscopy ; Optical properties ; BiFeO₃
• 刊名：Journal of the European Ceramic Society
• 出版年：2007
• 出版时间：2007
• 年：2007
• 卷：27
• 期：2-3
• 页码：937-940
• 全文大小：167 K

文摘

Multiferoic materials (having coupled electric, magnetic and structural order parameters that result in simultaneous ferroelectricity, ferromagnetism, and ferroelasticity) present opportunities for potential application in information storage, the emerging field of spinotronics and sensors. The perovskite BiFeO₃ is ferroelectric [Curie temperature (T_c) 1103 K] and antiferromagnetic [Neél temperature (T_N) 643 K], exhibiting weak magnetism at room temperature. Conditions for synthesizing single BiFeO₃ phase are critical since the temperature stability range of the phase is very narrow. Moreover, it is also difficult to control oxygen stoichiometry in the sample.

In this work the preparation of BiFeO₃ thin films by a specific wet chemical route is discussed. Respective influence of the precursors, thermal annealing condition, the substrate and, generally speaking, the preparation process of the films is presented.

Results obtained by X-ray diffraction and spectroscopic elipsometer (SE) was used to characterize the obtained films.