Interface Microstructure and Formation Mechanism of Diamond Abrasives Laser Brazed with Ni-Cr Solder

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• 作者：Yang Zhibo ; ^{yangzhibo2001@163.com" class="auth_mail" title="E-mail the corresponding author} ; Liu Aiju ; Yang Ruiyun ; Zhang Zhen ; Liu Shian
• 关键词：laser brazing ; Ni-based alloy ; interface microstructure ; reaction mechanism
• 刊名：Rare Metal Materials and Engineering
• 出版年：2016
• 出版时间：May 2016
• 年：2016
• 卷：45
• 期：5
• 页码：1152-1156
• 全文大小：1891 K

文摘

The laser brazing of diamond abrasives was investigated using Ni-based solder in an Ar atmosphere. The microstructure and the phase composition of the interface between diamond abrasives and Ni-based solder were analyzed using scanning electronic microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD). Meanwhile, the formation mechanism of carbides at the interface between solder and diamond abrasives was discussed. The results indicate that during laser brazing, the Cr-enriched layer around the diamond surface reacts with C in the diamond surface and consequently Cr₃C₂ is formed. Based on reaction thermodynamic and kinetic analysis, it is revealed that the interface reaction products can be formed via replacement reaction, which realize the tight combination between diamond abrasives and solder.