On the kinetics of the methanation of carbon dioxide on coprecipitated NiAl(O)x
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- 作者：Franz Koschanya ; b ; 1 ; David Schleretha ; b ; 1 ; Olaf Hinrichsena ; b ; olaf.hinrichsen@ch.tum.de" class="auth_mail" title="E-mail the corresponding author
- 关键词：Methanation ; Sabatier reaction ; Nickel&ndash ; alumina catalysts ; Carbon dioxide ; Intrinsic kinetics
- 刊名：Applied Catalysis B: Environmental
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：181
- 期：Complete
- 页码：504-516
- 全文大小：1863 K
文摘
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Preparation of coprecipitated NiAl(O)x methanation catalysts.
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Investigation of intrinsic kinetics at industrially relevant reaction conditions.
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Evaluation of power law, power law with inhibition and LHHW-type rate equations.
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Identification of product inhibition at high product gas content.
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Prediction of kinetics from differential conversion to equilibrium by chosen model.