Interplay between nitronates and nitriles accomplished in a PtIV-mediated reaction
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- 作者：Nadezhda A. Bokach ; Sema L. Ioffe ; Fedor M. Dolgushin ; Mikhail Yu. Antipin ; Vladimir A. Tartakovskii ; Vadim Yu. Kukushkin
- 关键词：Nitronates ; Nitriles ; Platinum(IV) complexes ; Ligand reactivity ; Metal-mediated reaction
- 刊名：Inorganic Chemistry Communications
- 出版年：2009
- 出版时间：February 2009
- 年：2009
- 卷：12
- 期：2
- 页码：173-176
- 全文大小：338 K
文摘
Reaction between the coordinated propanenitriles in trans-[PtCl4(EtCN)2] and the cyclic nitronate (1) gives the N-acylated iminocomplex (2) which is unstable in wet solvents and undergoes hydrolysis to furnish (3). The formulation of 2 and 3 was supported by satisfactory C, H, and N elemental analyses, agreeable HRESI+-MS, IR, 1H NMR spectroscopies, and single-crystal X-ray diffraction (for trans-3).