Sustainable carbon-carbon bond formation catalyzed by new oxamate-containing palladium(II) complexes in ionic liquids

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• 作者：Francisco Ram¨®n Fortea-P¨¦rez ; Isabel Schlegel ; Miguel Julve ; Donatella Armentano ; Giovanni De Munno ; Salah-Eddine Stiriba
• 关键词：Palladium(II) oxamates ; Ionic liquids ; C&ndash ; C cross-coupling ; Homogenous catalysis ; Sustainable chemistry
• 刊名：Journal of Organometallic Chemistry
• 出版年：2013
• 出版时间：15 October, 2013
• 年：2013
• 卷：743
• 期：Complete
• 页码：102-108
• 全文大小：862 K

文摘

New and versatile bis(oxamato)palladate(II) complexes of formula (n-Bu₄N)₂[Pd(2-Mepma)₂]¡¤4H₂O (1a) and (n-Bu₄N)₂[Pd(4-Mepma)₂]¡¤2H₂O¡¤MeCN (1b) (n-Bu₄N⁺?=?tetra-n-buthylammonium, 2-Mepma?=?N-2-methylphenyloxamate and 4-Mepma?=?N-4-methylphenyloxamate) have been synthesized and characterized by spectroscopic methods and single crystal X-ray diffraction. Each palladium(II) ion in 1a and 1b is four-coordinate with two oxygen and two nitrogen atoms from two fully deprotonated oxamate ligands building a centrosymmetric square planar surrounding. Their catalytic role has been investigated for both Heck and Suzuki coupling reactions using a series of aryl iodide/bromide derivatives in tetra-n-butylammonium bromide (n-Bu₄NBr) as ionic liquid, i.e. molten salt. These precatalysts appear as highly efficient, easily recovered and reused at least eight times without any drastic loss of their exceptional reactivity or leaching from the ionic liquid medium.