Unprecedented polymeric trifluoroacetate palladium-silver complexes: π-complex with η²- and η⁴-coordinated toluene, as well as a unique seventeen nuclear palladium-silver trifluoroacetate

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• 作者：Andrei V. Churakov ; Inessa A. Efimenko ; ^{ines@igic.ras.ru" class="auth_mail" title="E-mail the corresponding author} ; Olga S. Erofeeva ; Ludmila G. Kuzmina ; Nina A. Ivanova
• 刊名：Mendeleev Communications
• 出版年：2016
• 出版时间：July-August 2016
• 年：2016
• 卷：26
• 期：4
• 页码：295-297
• 全文大小：407 K

文摘

The first polynuclear heterodimetallic Pdⁱⁱ–Agⁱ trifluoroacetate π-complex with Agⁱ η²- and η⁴-coordinated molecules of toluene, namely, PdAg₂(μ-TFA)₄(η²-Tol)₂(μ-η⁴-Tol)]_n and [Pd₂Ag₄(μ-TFA)₈(η²-Tol)₂(μ-η⁴-Tol)]_n (TFA = OCOCF₃, Tol = toluene) as well as the unique seventeen nuclear Pdⁱⁱ–Agⁱ trifluoroacetate complex Pd₅Ag₁₂(H₂O)₁₆(μ-TFA)₈·7H₂O have been synthesized. Their solid-state structure was determined by X-ray method.