Structure-reactivity relationships of novel monomeric photoinitiators
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- 作者：Sesil Agopcan Cınara ; Melek Naz Guvena ; Tugce Nur Erena ; Belgin Cesura ; Mina Aleksanyana ; Burcu Dedeoglua ; Neren Oktea ; Viktorya Aviyentea ; Fabrice Morlet-Savaryb ; Jacques Lalevé ; eb ; Duygu Avcia ; avcid@boun.edu.tr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Photopolymerization ; Synthesis ; Irgacure 2959 ; Photoinitiators
- 刊名：Journal of Photochemistry & Photobiology, A: Chemistry
- 出版年：2016
- 出版时间：1 October 2016
- 年：2016
- 卷：329
- 期：Complete
- 页码：77-87
- 全文大小：2223 K
文摘
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Two different groups of methacrylates based on Irgacure 2959, Irgacure 184, benzophenone and acetophenone were synthesized.
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Photopolymerization efficiency of the initiators was determined using photo-DSC.
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The effect of polymerizable group structure on photoinitiation efficiency was found to be minimal for fast polymerizing systems.
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Irgacure 2959, Irgacure 184 and BP-based MPIs showed similar or increased activity compared to their commercial analogs.