Catalytic performance of imidazolium based ILs in the reaction of 1,2-epoxyoctane and carbon dioxide: Kinetic study
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- 作者：Pooja Jaiswal jaiswal2503@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Mahesh N. Varma ; maheshnvarma@gmail.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Cycloaddition reaction ; Cyclic carbonate ; Supercritical CO2 ; Epoxide ; Ionic liquid
- 刊名：Journal of CO2 Utilization
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：14
- 期：Complete
- 页码：93-97
- 全文大小：564 K
文摘
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Kinetics of cycloaddition reaction catalyzed by ionic liquids evaluated.
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Potential of ionic liquids utilized under supercritical CO2.
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Catalytic activity enhances with increasing alkyl chain length of cation.
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Tetrafluoroborate anion has better catalytic activity compared to bromide anion.
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1-hexyl-3-methylimidazolium tetrafluoroborate has lowest activation energy.