Simultaneous qualitative and quantitative analysis of fluoroalkyl sulfonates in riverine water by liquid chromatography coupled with Orbitrap high resolution mass spectrometry
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- 作者：Yongfeng Lin ; Runzeng Liu ; Fanbao Hu ; Ruirui Liu ; Ting Ruan ; tingruan@rcees.ac.cn" class="auth_mail" title="E-mail the corresponding author ; Guibin Jiang
- 关键词：Perfluoroalkyl sulfonates ; Fluorotelomer sulfonates ; LC&ndash ; MS/MS ; High resolution mass spectrometry ; Tribrid Orbitrap ; Riverine water
- 刊名：Journal of Chromatography A
- 出版年：2016
- 出版时间：26 February 2016
- 年：2016
- 卷：1435
- 期：Complete
- 页码：66-74
- 全文大小：1690 K
文摘
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Simultaneous qualitative and quantitative analysis of PFSAs by Orbitrap was tested.
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Quantification of PFOS isomers based on full-scan MS1 chromatogram.
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Competent linear dynamic range and sensitivity were found in the HRMS method.
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Accurate mass measurement had advantage on elimination of environmental interferent.
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High proportions of the emerging 6:2Cl-PFAES were found in riverine water samples.