The first octanuclear tin(IV)–oxosulfide cluster

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• 作者：Wu ; Liming ; Chen ; Ling ; Dai ; Jingcao ; Cui ; Chuanpeng ; Fu ; Zhiyong ; Wu ; Xintao
• 关键词：Tin(IV)&ndash ; oxosulfide complex ; Thiophenol ; DMF ; Crystal structures
• 刊名：Inorganic Chemistry Communications
• 出版年：2001
• 出版时间：October, 2001
• 年：2001
• 卷：4
• 期：10
• 页码：574-576
• 全文大小：113 K

文摘

The first octanuclear tin(IV)–oxosulfide complex (NH₄)₂(Et₄N)₄[Sn₈S₁₂O₄(SPh)₆] has been synthesized by mixing stoichiometric amount of Sn(SPh)₄ and (NH₄)₂WOS₃ and thiophenol in DMF. The compound was crystallized in orthorhombic space group Cmcm, Z=4,a=18.0463(4)A,b=15.7599(2)A,c=19.1914(5)A, a single crystal X-ray diffraction analysis revealed two coordinate modes of the tin atoms: five-coordinated distorted rectangular pyramid SnOS₄ and six-coordinated octahedron SnO₃S₃.