NiIII-embedded polyoxovanadate: Synthesis, structure and magnetic properties
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- 作者：Gaigai Wang ; Pengtao Ma ; Dongdi Zhang ; Jingyang Niu ; jyniu@henu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Jingping Wang
- 关键词：Polyoxovanadates ; Crystal structure ; Chemical synthesis ; Electrochemical properties ; Magnetic properties
- 刊名：Journal of Alloys and Compounds
- 出版年：2016
- 出版时间：25 November 2016
- 年：2016
- 卷：686
- 期：Complete
- 页码：1032-1036
- 全文大小：1105 K
文摘
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Pseudosandwich-type POV K2H5[NiIIIV14O40]·19H2O (1) was synthesized, characterized.
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Magnetic studies indicate that antiferromagnetic interaction exists in compound 1.
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Compound 1 is the first example of NiIII-containing POV and the second 3d transition metal embedded tetradecavanadate.