Substituent effect of fluorine atom on benzothiadiazole bridging unit in dye sensitized solar cells

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• 作者：Nara Cho ; Jinjoo Han ; Kihyung Song ; Moon-Sung Kang ; Moo-Jin Jun ; Youngjin Kang ; Jaejung Ko
• 关键词：Dye sensitized solar cells ; Organic sensitizer ; Fluorine substitution ; Benzothiadiazole ; Substituent effect
• 刊名：Tetrahedron
• 出版年：14 January, 2014
• 年：2014
• 卷：70
• 期：2
• 页码：427-433
• 全文大小：1084 K

文摘

Dye sensitized solar cells performances using two organic dyes with fluorinated-benzothiadiazole spacer, 3-{5-[7-(5-{4-[Bis(9,9-dimethyl-9H-fluoren-2-yl)-amino]-5-fluoro-phenyl}thiophen-2-yl)benzo-[1,2,5]thiadiazol-4-yl]thiophen-2-yl}-2-cyano acrylic acid (JK-311) and 3-{5-[7-(5-{4-[Bis(9,9-dimethyl-9H-fluoren-2-yl)-amino]-5,6-difluorophe-nyl}thiophen-2-yl)benzo-[1,2,5]thiadiazol-4-yl]thiophen-2-yl}-2-cyano acrylic acid (JK-312), were systematically investigated by solar simulation equipment, stepped light-induced transient measurements of photocurrent and voltage, and electrochemical impedance spectroscopy. To investigate substituent effect of fluorine atom on benzothiadiazole, molecular orbital calculations of two dyes using a time dependent density functional theory model with B3LYP/3-31G* were also carried out. JK-312 showed a unique electronic transition from HOMO-1 to LUMO. Short circuit current and open-circuit voltage in DSSCs performances were increased by the introduction of fluorine atom into spacer segment, compared to fluorine-free dyes.