Ground state and excited state dipole moments of 6,8-diphenylimidazo[1,2-α]pyrazine determined from solvatochromic shifts of absorption and fluorescence spectra
文摘
Electronic absorption and dual fluorescence spectra of 6,8-diphenylimidazo[1,2-α]pyrazine (68DIP) was recorded in various solvents with different polarity at room temperature. The ground state (μg) and the excited state (μg) dipole moments of 68DIP were estimated from solvatochromic shifts of absorption and fluorescence spectra as a function of the dielectric constant () and refractive index (n). The results show that the value of excited state dipole moment in SE: D and twisted intramolecular charge transfer (TICT) excited equilibrated state dipole moment value of D was found. The solvent dependent spectral shifts in absorption and fluorescence spectra were analyzed by the polarizabilityx2013;polarity and Kamletx2013;Taft parameters.