Synthesis, crystal structure, vibrational and ³¹P-NMR spectroscopy of the thiophosphate NaMg[POb>3b>S]·9Hb>2b>O

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• 作者：Henning A. Hö ; ppe^a ; ^{henning@ak-hoeppe.de} ; Stefan W. Scharinger^a ; Joachim G. Heck^b ; Peter Gross^a ; Philip Netzsch^a ; Karolina Kazmierczak^a
• 关键词：Thiophosphates ; Magnesium ; Sodium ; Vibrational spectroscopy ; Solid-state NMR spectroscopy ; Crystal structure
• 刊名：Solid State Sciences
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：62
• 期：Complete
• 页码：50-55
• 全文大小：1208 K
• 卷排序：62

文摘

Crystal structure determination of the first thiosulphate containing magnesium. Proof of presence of P-S bonds by vibrational and n.m.r. spectroscopies. Identification of a topotactic disorder-order phase transition occurring around 220 K. Crystal structure determination of the low temperature phase.