Synthesis, structure and thermal stability of a crown ether complexed K/Cl carbenoid

详细信息    查看全文

• 作者：Sebastian Molitor ; Viktoria H. Gessner ; ^{viktoria.gessner@rub.de}
• 关键词：Carbenoid ; Potassium ; Structure stability relationship ; Structure elucidation ; Carbanion
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：457
• 期：Complete
• 页码：29-33
• 全文大小：595 K
• 卷排序：457

文摘

A crown-ether complexed K/Cl carbenoid was isolated. Crown-ether coordination results in the cleavage of the K–Cl interaction in the carbenoid. The crown ether adduct possesses a higher stability than the THF coordinated analogue.