A Single-Event MicroKinetic model for the cobalt catalyzed Fischer-Tropsch Synthesis
详细信息 查看全文
- 作者：Jonas Van Belleghema ; Jonas.VanBelleghem@Ugent.be" class="auth_mail" title="E-mail the corresponding author ; Cristian Ledesmab ; cristian.l.rodriguez@ntnu.no" class="auth_mail" title="E-mail the corresponding author ; Jia Yangc ; Jia.Yang@sintef.no" class="auth_mail" title="E-mail the corresponding author ; Kenneth Tocha ; Kenneth.Toch@Ugent.Be" class="auth_mail" title="E-mail the corresponding author ; De Chenb ; chen@ntnu.no" class="auth_mail" title="E-mail the corresponding author ; Joris W. Thybauta ; Joris.Thybaut@Ugent.be" class="auth_mail" title="E-mail the corresponding author ; Guy B. Marina ; Guy.Marin@Ugent.Be" class="auth_mail" title="E-mail the corresponding author
- 关键词：Fischer-Tropsch Synthesis ; Single-Event MicroKinetic modeling ; Cobalt catalyst ; UBI-QEP ; CO hydrogenation
- 刊名：Applied Catalysis A: General
- 出版年：2016
- 出版时间：25 August 2016
- 年：2016
- 卷：524
- 期：Complete
- 页码：149-162
- 全文大小：1075 K
文摘
- •
Validation of Single-Event MicroKinetic methodology for the Co catalyzed Fischer-Tropsch Synthesis.
- •
The adjustable parameters are all statistically significant and physicochemical meaningful.
- •
Deviations from Anderson-Schulz-Flory distribution are explained by symmetry and adsorption effects.
- •
Activity difference between Fe and Co catalysts is interpreted in terms of the oxygen atomic chemisorption enthalpy.