Synthesis of indol-3-yl aryl ketones through visible-light-mediated carbonylation

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• 作者：Hong-Tao Zhang^a ; Li-Jun Gu^a ; ^b ; ^{gulijun2005@126.com" class="auth_mail" title="E-mail the corresponding author} ; Xiang-Zhong Huang^a ; Rui Wang^a ; Cheng Jin^c ; Gan-Peng Li^a ; ^{ganpeng_li@sina.com" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Indol-3-yl aryl ketones ; Carbonylation ; Visible-light ; Aryldiazonium salts ; Indoles
• 刊名：Chinese Chemical Letters
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：27
• 期：2
• 页码：256-260
• 全文大小：2461 K

文摘

A visible-light-catalyzed synthesis of indol-3-yl aryl ketones from aryldiazonium salts, CO and indoles at room temperature was developed. This process provides a useful method for the preparation of diverse indol-3-yl aryl ketones from readily accessible reactants under base-free, acid-free and transition-metal-free conditions.