Thermodynamics of hydrogen bonding and van der Waals interactions of organic solutes in solutions of imidazolium based ionic liquids: “Structure-property” relationships
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- 作者：Mikhail A. Varfolomeev ; vma.ksu@gmail.com" class="auth_mail" title="E-mail the corresponding author ; mikhail.varfolomeev@kpfu.ru" class="auth_mail" title="E-mail the corresponding author ; Artashes A. Khachatrian ; Bulat S. Akhmadeev ; Boris N. Solomonov
- 关键词：Hydrogen bond ; van der Waals interactions ; Solution calorimetry ; Enthalpy of solution ; Enthalpy of solvation ; Ionic liquid ; Solvent scale
- 刊名：Thermochimica Acta
- 出版年：2016
- 出版时间：10 June 2016
- 年：2016
- 卷：633
- 期：Complete
- 页码：12-23
- 全文大小：1260 K
文摘
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Solution enthalpies of organic solutes in imidazolium based ionic liquids were measured.
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van der Waals interactions scale of imidazolium based ionic liquids was proposed.
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Enthalpies of solvation of organic solutes in ionic liquids were determined.
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Hydrogen bond enthalpies of organic solutes with ionic liquids were calculated.
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Relationships between structure of ionic liquids and thermochemical data were obtained.