Growth, structural, optical and mechanical studies on acid mixed glycine metal salt (GABN) crystal as potential NLO material

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• 作者：Mahendra M. Khandpekar^a ; Shailesh S. Dongare^b ; ^{shaileshdongare@yahoo.co.in} ; Shirish B. Patil^c ; Shankar P. Pati^d
• 关键词：Crystal growth ; Structure ; Non linear optical ; Hardness
• 刊名：Optics Communications
• 出版年：2012
• 出版时间：15 March 2012
• 年：2012
• 卷：285
• 期：6
• 页码：1253-1258
• 全文大小：786 K

文摘

Transparent crystals of ¦Á-glycine with ammonium nitrate and barium nitrate (GABN) have been grown from aqueous solution by slow evaporation technique at room temperature. Crystals of size 11 ¡Á 7 ¡Á 4 mm³ have been obtained in about 3-4 weeks time. The solubility of GABN has been determined in water. The grown crystal belongs to orthorhombic system with cell parameters a = 7.317 A.U, b = 12.154 A.U and c = 5.468 A.U with a unit cell volume 486.35 (A.U)³. The presence of chemical components/groups has been identified by CHN, EDAX and NMR analysis. Comparative IR and Raman studies indicate a molecule with a lack of centre of symmetry. A wide transparency window useful for optoelectronic applications is indicated by the UV Studies. Using a Nd-YAG laser (1064 nm), the optical second harmonic generation (SHG) conversion efficiency of GABN is found to be 1.406 times of that of standard KDP. On exposure to light the GABN crystals are found to exhibit negative photoconductivity. I-V characteristics, SEM studies, dielectrics studies, and Vickers micro hardness measurement have been carried out.