Synthesis of high molecular weight linear and branched polylactides: A comprehensive kinetic investigation
详细信息 查看全文
- 作者：Konstantina Karidia ; Theofanis Mantourliasa ; b ; Antonios Seretisa ; b ; Prokopios Pladisa ; Costas Kiparissidesa ; b ; costas.kiparissides@cperi.certh.gr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ring-opening polymerization of l ; l-lactide ; Co-initiator ; High molecular weight polylactides ; Kinetic study ; Molecular ; Thermal and mechanical properties
- 刊名：European Polymer Journal
- 出版年：2015
- 出版时间：November 2015
- 年：2015
- 卷：72
- 期：Complete
- 页码：114-128
- 全文大小：1324 K
文摘
- •
The ROP of l,l-lactide in the presence of polyalcohols is investigated.
- •
Experimental results on polymerization rate and MWD for different co-initiators.
- •
Assessment of the hydroxyl groups reactivity for different polyalcohols.
- •
High molecular weight linear and non-linear polylactides were synthesized.
- •
Tailor-made PLLA was synthesized with desired end-use properties.