Reliable rate constant determination for heterogeneous electron transfer: CrEDTA^–

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• 作者：Alex ; er S. Kotkin ; Alex ; er G. Krivenko ; Galina N. Botukhova ; Galina A. Tsirlina
• 刊名：Mendeleev Communications
• 出版年：2009
• 出版时间：November-December 2009
• 年：2009
• 卷：19
• 期：6
• 页码：314-316
• 全文大小：358 K

文摘

Pulse and steady-state photoemission techniques are applied to determine the heterogeneous rate constant of CrEDTA– reduction on liquid mercury. The resulting value (too high for polarographic determination and available earlier only for amalgamated gold) is important for experimental verification of various predictions of the electron transfer theory.