Pd(II) complexes based on quinoline derivative: Structural characterization and their role as a catalyst for hydrogenation of (E)-1-methyl-4-(2-nitrovinyl)benzene

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• 作者：Mohammad Azam ; Mohammad Shahidul Islam ; Saud I. Al-Resayes ; M. Rafiq Siddiqui ; Agata Trzesowska-Kruszynska ; Rafal Kruszynski
• 关键词：(z)-2-((Quinolin-3-ylimino)methyl)phenol ; Crystal structure ; Pd(II) complexes ; Hydrogenation
• 刊名：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
• 出版年：5 April, 2014
• 年：2014
• 卷：123
• 期：Complete
• 页码：1-6
• 全文大小：595 K

文摘

A series of two new Pd(II) complexes with ligand, HL, (z)-2-((quinolin-3-ylimino)methyl)phenol, derived from 3-aminoquinoline and 2-hydroxybenzaldehyde was reported. The structure of ligand, HL was determined by single crystal X-ray diffraction. The ligand, HL crystallizes in the space group P2₁/n of the monoclinic system with unit cell dimensions a = 8.8733(8), b = 6.3318(5), c = 11.5145(9). The reaction of ligand, HL with PdX₂ [X = Cl^{鈭?/sup>, OAc] in 2:1 molar ratio yielded complexes of the type [Pd(HL)₂X₂] [X = Cl鈭?/sup>, OAc]. The ligand, HL and its Pd(II) complexes were characterized by various physico-chemical techniques; elemental analyses, ionization mass spectrometry (ESI-MS), UV/Vis, FT-IR, 1H and 13C NMR spectroscopy. UV/Vis absorption studies showed a square planar geometry around Pd (II) ion. The selective hydrogenation of (E)-1-methyl-4-(2-nitrovinyl)benzene in ethanol using synthesized Pd(II) complexes as catalysts was investigated at room temperature. The Pd(II) complexes catalyzed the hydrogenation of (E)-1-methyl-4-(2-nitrovinyl)benzene to (E)-1-methyl-4-(2-aminovinyl) benzene. Furthermore, the catalytic activity increased with increasing the quantity of Pd(II) complexes as catalysts.}