Syntheses of bimetallic rare-earth bis(cyclopentadienyl) derivatives supported by bridged bis(guanidinate) ligands and their catalytic property for the hydrophosphonylation of aldehydes
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- 作者：Kun Niea ; b ; nkniekun@163.com" class="auth_mail" title="E-mail the corresponding author ; Chengwei Liua ; Yong Zhanga ; Yingming Yaoa ; yaoym@suda.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Rare-earth metal complex ; Bis(guanidinate) ligand ; Hydrophosphonylation reaction ; Aldehyde
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 February 2016
- 年：2016
- 卷：804
- 期：Complete
- 页码：59-65
- 全文大小：790 K
文摘
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Five new bimetallic organo-rare-earth metal complexes were synthesized.
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The structures were elucidated by X-ray crystallography.
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These complexes showed high catalytic activity for hydrophosphonylation reaction under mild conditions.