Evaluation of thermodynamic consistency of isobaric and isothermal binary vapor–liquid equilibrium data using the PAI test
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- 作者：Kurihara ; Kiyofumi ; Egawa ; Yusuke ; Ochi ; Kenji ; Kojima ; Kazuo
- 关键词：Vapor&ndash ; liquid equilibria ; data ; Vapor&ndash ; liquid&ndash ; liquid equilibria ; Thermodynamic consistency ; Gibbs energy ; activity coefficient
- 刊名：Fluid Phase Equilibria
- 出版年：2004
- 出版时间：May 10, 2004
- 年：2004
- 卷：219
- 期：1
- 页码：75-85
- 全文大小：138 K
文摘
The aim of this work is to evaluate the thermodynamic consistency (TC) of binary vapor–liquid equilibrium (VLE) data at low pressure using the PAI test proposed in our previous study. In this work, the PAI test was incorporated with the NRTL equation for fitting data. The PAI test permits an overall check of the data by combining three tests: the point test, the area test, and the infinite dilution test.