Interleaved and entangled divalent metal thiophenedicarboxylate coordination polymers with an extremely long-spanning and flexible dipyridylamide ligand
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- 作者：Alexander D. Sample ; Robert L. LaDuca ; laduca@msu.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Coordination polymer ; X-ray diffraction ; Self-catenation ; Cobalt ; Cadmium ; Nickel
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：24 March 2016
- 年：2016
- 卷：443
- 期：Complete
- 页码：198-206
- 全文大小：3733 K
文摘
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Divalent metal coordination polymers with 2,5-thiophenedicarboxylic acid (H2tdc).
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Inclusion of very long spanning dipyridylamide ligand 4-ppbp.
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Copper derivative has slab topology with pairs of interleaved (4,4) layer motifs.
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Cobalt derivative has tubular structure with rare 1D + 1D → 2D parallel polycatenation.
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Nickel derivative has unprecedented system of interpenetrated (4,4)IIb layers.