Fast oxidation of secondary alcohols by the bromate-bromide system using cyclic microwave heating in acidic water
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- 作者：Sanna Pä ; ä ; kkö ; nen ; Jouni Pursiainen ; Marja Lajunen
- 关键词：Microwave heating ; Alcohol oxidation ; Water ; Green chemistry
- 刊名：Tetrahedron Letters
- 出版年：2010
- 出版时间：22 December 2010
- 年：2010
- 卷：51
- 期：51
- 页码：6695-6699
- 全文大小：1740 K
文摘
We report an improved, gentle, cyclic microwave activation technique for the oxidation of secondary alcohols using nonhazardous hypobromous acid (BrOH) as the reagent in acidic water. Several aliphatic and aromatic secondary alcohols were successfully oxidized to the corresponding ketones using this technique in high yields and with only minor amounts of side products.