Preparation of NHC–ruthenium complexes and their catalytic activity in metathesis reaction
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- 作者：Evelina Colacino ; Jean Martinez ; Fré ; dé ; ric Lamaty
- 关键词：N-Heterocyclic carbenes ; Homogeneous ruthenium catalysts ; Supported ruthenium catalysts ; RCM mechanism
- 刊名：Coordination Chemistry Reviews
- 出版年：2007
- 出版时间：March 2007
- 年：2007
- 卷：251
- 期：5-6
- 页码：726-764
- 全文大小：2024 K
文摘
A detailed overview on the synthesis of four-, five- and six-membered, saturated and unsaturated N-heterocyclic carbenes used in the preparation of their corresponding ruthenium complexes (Grubbs’ second-generation, Fischer-type, Hoveyda–Grubbs, homo and hetero-bimetallic) is presented both in solution and on solid support. The catalytic activity of the different complexes in ruthenium-catalyzed metathesis reaction is compared and explained by their structural features.