Catalytic oxidation of alcohols to aldehydes or ketones using osmium–oxo complexes with sulfoxides or N-methylmorpholine-N-oxide as the co-oxidant: a comparative study

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• 作者：Coleman ; Karl S. ; Bedel ; Laurent J.L. ; Osborn ; John A.
• 关键词：catalysis ; oxidation ; osmium ; alcohol ; sulfoxide ; catalyse ; oxydation ; osmium ; alcool ; sulfoxyde
• 刊名：Comptes Rendus de l'Academie des Sciences Series IIC Chemistry
• 出版年：2000
• 出版时间：January 1, 2000
• 年：2000
• 卷：3
• 期：10
• 页码：765-769
• 全文大小：191 K

文摘

A catalytic amount of osmium tetroxide in association with sulfoxides or N-methylmorpholine-N-oxide can be used to catalyse the oxidation of primary and secondary alcohols to their corresponding carbonyl compounds.