Microwave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexes
详细信息 查看全文
- 作者：Marisol Ledezma-Gairaud ; Leslie W. Pineda ; Guillem Arom¨ª ; E. Carolina Sa?udo
- 关键词：George Christou 60th birthday special issue ; Coordination chemistry ; Microwave assisted synthesis ; Magnetism
- 刊名：Polyhedron
- 出版年：2013
- 出版时间：12 November, 2013
- 年：2013
- 卷：64
- 期：Complete
- 页码：45-51
- 全文大小：941 K
文摘
Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. Using bench-top, the mixed metal Mn/Ni complex [Mn5Ni4(OH)4(C5H12NO)4(SALOH)6(SALO)4] (complex 1) is obtained while the microwave reactor affords a Mn7 complex, [Mn7(OH)3(C5H12NO)2(C5H13NO)(SALO)6(SALOH)3] complex 2, where the Ni(II) has not been incorporated or a Mn2Ni2 cubane, [Pr2NH2][Mn2Ni2(OH)2(C5H12NO)2(SALO)3(SALOH)2] complex 3.