Modification of firefly cyclic amino oxyluciferin analogues emitting multicolor light for OLED and near-Infrared biological window light for bioluminescence imaging: A theoretical study

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• 作者：Chun-Gang Min^a ; ^{minchungang@163.com} ; Yan Leng^b ; Yan-Qin Zhu^a ; Xi-Kun Yang^a ; Shao-Jun Huang^a ; Ai-Min Ren^c
• 关键词：OLED ; Multicolor light-emitting materials ; Near-infrared biological window light ; TDDFT ; Cyclic amino oxyluciferin analogues
• 刊名：Journal of Photochemistry and Photobiology A: Chemistry
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：336
• 期：Complete
• 页码：115-122
• 全文大小：1414 K
• 卷排序：336

文摘

The introduction of double bond is effective approach to change the emission color. The fluorescent scope of the studied compounds in DMSO termed near-infrared region. Cycoxyluc1d and cycoxyluc2d can be used as red light-emitting materials for OLED. Insert of double bond largely improves the ability of hole and electron injection. The substituent of −F group largely improves the electron injection ability.