An all-solid-state Z-scheme photocatalyst BiVO4/RGO/Bi2O3 was synthesized.
The obtained BiVO4/RGO/Bi2O3 displayed the strongest visible light harvest.
RGO interlayer plays an important role in charge carriers separation.
Photocatalytic mineralization of indoor toluene was carried out upon visible light.
The photocatalytic mineralization rate of BiVO4/RGO/Bi2O3 arrived to 95.6%.