Peroxide-mediated direct synthesis of amides from aroyl surrogates

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• 作者：Gang Hong ; Shengying Wu ; Xiaoyan Zhu ; Dan Mao ; Limin Wang ; ^{wanglimin@ecust.edu.cn" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Azobenzenes ; Synthetic methods ; Radical reaction
• 刊名：Tetrahedron
• 出版年：2016
• 出版时间：21 January 2016
• 年：2016
• 卷：72
• 期：3
• 页码：436-441
• 全文大小：783 K

文摘

An efficient and metal-free method has been developed for the direct synthesis of amides from readily available azobenzenes reacting with aroyl surrogates such as alcohols, methylarenes. A variety of amides were afforded in moderate to good yields through this reaction. It is another example reported by our group for the use of azobenzene as the new radical acceptor.